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filingDate 2020-09-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3ce2e49f89377efc679a105be266a587
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publicationDate 2021-04-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2021102066-A1
titleOfInvention Mechanoresponsive polymers exhibiting low-energy molecular switching
abstract Tunable negative thermal expansion linear polymer materials with reversible large-scale mechanoresponse under low-energy stimulation and fabrication methods are provided. The reversible thermal contraction of the material is due to a molecular switch, s-dibenzocyclooctadiene (DBCOD), which undergoes a twist-boat to chair conformational change when heated or radiated by near-infrared light. The DBCOD moieties are present as either crosslinkers or polymer main-chain units and the corresponding polymers can have different amounts of DBCOD units in the polymer main chain. The various DBCOD monomers can be covalently incorporated into a variety of polymeric materials to construct negative thermal expansion or zero expansion materials for the specific applications.
priorityDate 2018-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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