http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2020095228-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0636bdd1effca4dd96f96f6f393f37a5 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D403-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D403-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D235-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-0086 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-02 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D403-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-00 |
filingDate | 2018-03-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1d86ac3db75e9645378b4e6c99155bb1 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0d28cd70350bf3abd1c1aa0f4970fc99 |
publicationDate | 2020-03-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-2020095228-A1 |
titleOfInvention | Unsymmetric ccc-nhc pincer metal complexes and methods of use thereof |
abstract | Provided herein are unsymmetrical bis(azolium) salts, unsymmetrical CCC-NHC metal complexes, and methods of forming the same. The unsymmetrical bis(azolium) salts include a central aryl ring that is substituted with two heterocyclic rings in an ortho, meta, or para fashion. The unsymmetrical CCC-NHC metal complexes include metalated unsymmetrical bis(azolium) salts. The method of forming the unsymmetrical CCC-NHC metal complexes includes reacting a dihalogenated benzene with a first azole to form a mono(azole)benzene, reacting the mono(azole)benzene with a second azole to form an unsymmetrical bis(azole)benzene, alkylating the unsymmetrical bis(azole)benzene to form an unsymmetrical bis(azolium) salt, and metalating the unsymmetrical bis(azolium) salt to form the unsymmetrical CCC-NHC metal complex. Also provided are a bis-ligated CCC-NHC metal complex and an unsymmetrical bimetallic complex. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2022112229-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11103861-B2 |
priorityDate | 2017-03-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 225.