| abstract |
The present invention relates to novel thermoplastic polyurethane (TPU) compositions that have crystalline chain ends. The TPU compositions of the invention can provide improved resiliency, lower surface free energy, and/or reduced stickiness, while maintaining other desirable physical properties. The TPU compositions of the present invention are made from the reaction product of an aliphatic polyisocyanate, a polycaprolactone polyester polyol, an optional chain extender component, and a chain terminator component, which comprises a short chain crystalline compound containing a single functional group capable of terminating the chain of the thermoplastic polyurethane. |