http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2018245179-A1

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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3839191397cd99776c6756be401e4720
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_46fa174ccb30b65e0db85db9ec055aa1
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publicationDate 2018-08-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2018245179-A1
titleOfInvention Method for Removing Arsenic from Materials Containing Same
abstract Process for the removal of arsenic from materials with a high arsenic content or materials with a high content in arsenic and selenium that comprises:n Adding the material to a pressurized reactor; Adding an alkaline lixiviating solution of a strong base dissolved in water to the reactor; Adding an oxidizing gas to the reactor; Mixing the above components in the reactor to obtain a homogenous pulp and subjecting it to a lixiviation under pressure that is selective for arsenic with respect to the other elements of interest present in the treated material; Subjecting the pulp obtained from the lixiviation step to a first solid-liquid separation step, thereby obtaining a liquor with dissolved arsenic and a solid with low arsenic content; Subjecting the liquor with dissolved arsenic to a precipitation of the arsenic with a precipitating agent, selecting compounds that supply the following cations: Ce 3+ , Fe 3+ , Mg 2+ , and a combination of Fe 3+ and Ca 2+ ; And, subjecting the product of the arsenic precipitation step to a second solid-liquid separation step, thereby obtaining a solid arsenic-containing product and an alkaline liquor free of arsenic. nn Optionally the process also comprises:n Subjecting the alkaline liquor free of arsenic to a sodium sulfate (Na 2 SO 4 ) crystallization step, thereby obtaining a pulp composed of Na 2 SO 4 crystals and an alkaline liquor free of Na 2 SO 4 ; Subjecting the product of the Na 2 SO 4 precipitation step to a third solid-liquid separation step, thereby obtaining a solid comprising Na 2 SO 4 crystals and an alkaline liquor.
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