| abstract |
A compound having a chemical formula according to Formula (I) is disclosed where one of Z 1 , Z 2 and Z 3 is and one of the Z 1 , Z 2 , and Z 3 that is bonded to a carbon atom that is adjacent to the carbon atom bonded to is P(AR 1 )(A′R 2 ). Metal-based catalyst and pre-catalysts, such as nickel-based catalysts and precatalysts, where the metal is complexed to the compound are also disclosed. Methods of forming C(sp2)-N bonds are also disclosed. |