abstract |
Aimed at providing a sulfide solid electrolyte comprising an argyrodite type crystal structure, having a high ionic conductivity due to presence of a large amount of a halogen element and is capable of suppressing agglomeration at the time of production. Provided is a sulfide solid electrolyte comprising lithium, phosphorus, sulfur and one or more elements X selected from halogen elements, wherein the sulfide solid electrolyte comprises an argyrodite type crystal structure, and wherein a molar ratio of the lithium to the phosphorus “a (Li/P)”, a molar ratio of the sulfur to the phosphorus “b (S/P)” and a molar ratio of the element X to the phosphorus “c (X/P)” satisfy the following formulas (1) to (3): n 5.05≦ a <7.3 (1)n n 0.705≦ a−b <1.0 (2)n n 7.0< a+c ≦7.3 (3)n n provided that b>0 and c>0. |