abstract |
The disclosure relates to a method for removing sulfur-containing compounds from a fluid. The method involves adding manganese oxide to the fluid; doping the manganese oxide in situ with iron, cobalt, or combinations thereof to give a doped manganese oxide adsorbent; and contacting the fluid with a selected amount of the doped manganese oxide adsorbent and at a selected temperature and pressure sufficient for the doped manganese oxide adsorbent to preferentially adsorb the sulfur-containing compounds in the fluid. The disclosure also relates to a process for preparing a doped manganese oxide adsorbent, and a doped manganese oxide adsorbent prepared by the process. The disclosure further relates to a method for tuning structural properties (e.g., surface area, pore size and pore volume) of a doped manganese oxide adsorbent. |