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publicationDate 2016-01-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2016028073-A1
titleOfInvention Positive electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery using the same
abstract [Object] Provided is a means for improving cycle characteristics by suppressing electrode deterioration resulting from non-uniformity of voltage across an electrode plane in a high-capacity and large-area non-aqueous electrolyte secondary battery that includes lithium nickel-based composite oxide as a positive electrode active substance. n [Solving Means] Disclosed is a positive electrode for a non-aqueous electrolyte secondary battery used in a non-aqueous electrolyte secondary battery in which the ratio value of battery area (projected area of the battery including the battery outer casing body) to rated capacity is 5 cm 2 /Ah or more and the rated capacity is 3 Ah or more, the positive electrode comprising a positive electrode current collector and a positive electrode active substance layer that is formed on a surface of the positive electrode current collector and has a positive electrode active substance containing a lithium nickel-based composite oxide and a spinel type lithium manganese composite oxide, in which, when the average secondary particle diameter (D 50 ) of the lithium nickel-based composite oxide is D 50 (A) [μm], the content ratio of the lithium nickel-based composite oxide in the positive electrode active substance layer is A [% by mass], the average secondary particle diameter (D 50 ) of the spinel type lithium manganese composite oxide is D 50 (B) [μm], and the content ratio of the spinel type lithium manganese composite oxide in the positive electrode active substance layer is B [% by mass], the positive electrode satisfies the following Mathematical Formula 1 and Mathematical Formula 2: n [Math. 1] n 0.5≦ D 50( A )/ D 50( B )≦2.0  MathematicalFormula1:n n B /( A+B )≧0.2  MathematicalFormula2:
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