http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2014295665-A1

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filingDate 2014-06-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7b0f05279b96341768130742ec03d63a
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publicationDate 2014-10-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2014295665-A1
titleOfInvention Method for removing native oxide and associated residue from a substrate
abstract Native oxides and associated residue are removed from surfaces of a substrate by sequentially performing two plasma cleaning processes on the substrate in a single processing chamber. The first plasma cleaning process removes native oxide formed on a substrate surface by generating a cleaning plasma from a mixture of ammonia (NH 3 ) and nitrogen trifluoride (NF 3 ) gases, condensing products of the cleaning plasma on the native oxide to form a thin film that contains ammonium hexafluorosilicate ((NH 4 ) 2 SiF 6 ), and subliming the thin film off of the substrate surface. The second plasma cleaning process removes remaining residues of the thin film by generating a second cleaning plasma from nitrogen trifluoride gas. Products of the second cleaning plasma react with a few angstroms of the bare silicon present on the surface, forming silicon tetrafluoride (SiF 4 ) and lifting off residues of the thin film.
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