http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2014275659-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1a34d7d2e0d09a58cb7bf4a04c81162e |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C19-01 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C21-04 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C17-25 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C17-42 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C17-25 |
filingDate | 2013-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_dd62a665c73ccc8ae9e9248a309a37cb http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0f4619b5726ebd09b5f1dcfdccc7cac3 |
publicationDate | 2014-09-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-2014275659-A1 |
titleOfInvention | Method to improve 1,1,3-trichloropropene and/or 3,3,3-trichloropropene selectivity during the dehydrochlorination of 1,1,1,3-tetrachloropropane |
abstract | This invention relates to a method to improve 1,1,3-trichloropropene (HCC-1240za) and/or 3,3,3-trichloropropene (HCC-1240zf) selectivity in the dehydrochlorination of 1,1,1,3-tetrachloropropane (HCC-250fb). In normal practice, FeCl 3 is used as the catalyst for the dehydrochlorination of HCC-250fb to produce 1,1,3-trichloropropene and/or 3,3,3-trichloropropene. The present invention demonstrates that when using FeCl 3 as the catalyst for 1,1,1,3-tetrachloropropane dehydrochlorination, the reaction product contains significant amounts of high boiling compounds, such as pentachlorocyclohexene and/or hexachlorocyclohexane species. The addition of one or more UV-stabilizer and/or anti-oxidant compounds, or mixtures thereof, into the dehydrochlorination reaction system, inhibits the formation of these high boiling compounds and improves selectivity to the desired product. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11358918-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019195250-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2019276379-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2017156306-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10934232-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10766838-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11325876-B2 |
priorityDate | 2013-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 345.