http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2013190510-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2a819eda0adf22936a52362eeebb9fb4 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_59de710efebddf44b9d8d274be0aff5f http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d401d65c36a937a6f25b6e83a38f8e05 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_77ee8578aa10479d07b3b04326a92f30 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F5-027 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F5-02 |
| filingDate | 2012-07-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1cb7f9e8efeb2a01ac68fdd52f3cc8f4 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5685555fa5e933545f2c41039d4fb62a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b4a9e17eaff704b3be04b0862c7fc109 |
| publicationDate | 2013-07-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | US-2013190510-A1 |
| titleOfInvention | Neutral Tricoordinate Organoboron Derivatives Isoelectronic with Amines and Phosphines |
| abstract | Amines and boranes are the archetypical Lewis bases and acids, respectively. The former can readily undergo one-electron oxidation to give radical cations, whereas the latter are easily reduced to afford radical anions. The present invention provides the synthesis of neutral tricoordinate boron derivatives, which act as a Lewis base, and undergoes one-electron oxidation into the corresponding radical cation. The present invention also provides borylene (H—B:) and borinylium (H—B + .) complexes stabilized by two cyclic (alkyl)(amino)carbenes. Ab initio calculations show that the HOMO [Highest Occupied Molecular Orbital] of the borane as well as the SOMO [Singly Occupied Molecular Orbital] of the radical cation are essentially a pair and a single electron in the p(π)-orbital of boron, respectively. |
| isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10700295-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-3350189-B1 |
| priorityDate | 2011-07-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 209.