http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2013030121-A1

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F110-06
filingDate 2012-10-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cd3a6a8edd40071c50727da527122839
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_682fb350107fd45d0dafc9f54af437a7
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8aa601c306db578e1efff47b86e8a971
publicationDate 2013-01-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2013030121-A1
titleOfInvention Methods of constructing alkene-based homopolymer polyolefins having reduced crystallinity
abstract The invention is a novel family of polyolefins characterized by chain-walking defects of the type that add extra backbone carbons per monomer. These polyolefins display a large decrease in crystallinity relative to polyolefins known in the art. Specifically, the reduction in crystallinity is much greater than for earlier polypropylenes with a matched content of stereo or 1-alkene type defects. The claimed polyolefins can be an alkene-based homopolymer. The defects in the polyolefin backbone are generated by a chain walking mechanism in which three or more carbons per monomer are added to the polymer backbone instead of two, as in conventional polymerization or copolymerization methods of alpha olefins. The novel polyolefins can be used in applications such as plastic wrapping, thin films, co-extrusion layers or molded parts in the absence of polymer blending or copolymerization. The cost of materials production can be reduced.
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