| abstract |
A process is described for the preparation of a functionalized hybrid solid with an organic-inorganic matrix, crystallized, bearing at least one reactive group based on a triazole ring, from a hybrid solid with an organic-inorganic matrix, MOF—NH 2 , comprising: i/ introduction, in a polar solvent S1, of said crystallized hybrid solid MOF—NH 2 , of at least one organic compound Q containing a nitride function N 3 and at least one intermediate reagent R containing a nitrite function NO 2 , ii/ reaction of said reaction mixture, iii/ introduction in the reaction mixture of at least one reagent A bearing an alkyne function or an activated cyanide function, at least one Cu-based catalyst C and at least one polar solvent S2, iv/ reaction of said reaction mixture, v/ filtration and then washing and vi/ drying of said crystallized functionalized hybrid solid. |