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publicationDate 2011-12-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2011319667-A1
titleOfInvention Reaction process utilizing critical
abstract In order to perform organic synthesis process through action with supercritical water and acid stably while suppressing a trouble caused by a by-product, a method and an apparatus are provided, including the following steps. Water is supplied to high-pressure pumps ( 110 ) and ( 210 ) from water headers ( 101 ) and ( 201 ), and a pressure-reducing valve ( 324 ) is regulated to increase the pressure to 35 MPa. Temperatures of preheaters ( 120 ) and ( 220 ) and a heater ( 310 ) are increased until the reaction solution is at a temperature of 400° C. Acid (sulfuric acid) and an organic compound raw material (glycerin) are supplied from an acid header ( 203 ) and a raw-material header ( 203′ ) for action with the supercritical water to obtain a reaction solution. The obtained reaction solution is cooled to 100 to 200° C. by first cooling ( 420 ) and a solid component included in the reaction solution is separated for removal from the reaction solution by a filter ( 320 ), and then the reaction solution is cooled to a temperature of about 100° C. or lower by second cooling ( 620 ) and pressure thereof is reduced ( 324 ). Further, the reaction solution is cooled by third cooling ( 720 ) and then a synthesized product (acrolein) is captured.
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