abstract |
The invention relates to addition compounds of a) alkylphosphonous acid derivatives of the formula A-P(═O)(OX)—H (I) in which A represents C 2 -C 18 -alkyl, C 2 -C 18 -alkylene, C 6 -C 18 -arylalkyl, C 6 -C 18 -arylalkyl, optionally substituted, and X represents H, C 1 -C 18 -alkyl, C 6 -C 18 -aryl, C 6 -C 18 -arylalkyl, C 6 -C 18 -alkylaryl, optionally substituted C 2 -C 18 -alkylene, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H and/or a protonated nitrogenous base, and b) diester-forming olefins of formula (II) n n n n n n n n n n in which R 2 , R 4 are identical or different from each other and represent CO 2 H, CO 2 R 5 , R 6 —CO 2 H, R 6 —CO 2 R 5 and R 1 , R 3 are identical or different from each other and represent H, R 5 ; or R 1 , R 4 are identical or different from each other and represent CO 2 H, CO 2 R 5 , R 6 —CO 2 H, R 6 —CO 2 R 5 and R 2 , R 3 are identical or different from each other and represent H, R 5 ; or R 2 , R 4 are identical or different from each other and represent —CO—O—CO—, —CO—S—CO—, —CO—NR 1 —CO—, —CO—PR 1 —CO— and R 1 , R 3 are identical or different from each other and represent H, R 5 ; or R 1 , R 2 are identical or different from each other and represent CO 2 H, CN, CO 2 R 5 , R 6 —CO 2 H, R 6 —CO 2 R 5 and R 3 , R 4 are identical or different from each other and represent H, R 5 ; or R 1 , R 2 are identical or different from each other and represent —CR 2 3 —CO—O—CO—, —CR 2 3 —CO—NR 1 —CO—, —CR 2 3 —CO—O—CO-CR 2 3 , —CR 2 3 —CO—NR 1 —CO—CR 2 3 and R 3 , R 4 are identical or different from each other and represent H, R 5 ; or R 2 and R 4 each represent —CO—CR 5 ═CR 5 —CO— and R 1 , R 3 are identical or different from each other and represent H, R 5 ; R 5 ═C 1 -C 18 -alkyl, C 6 -C 18 -aryl, C 6 -C 18 -arylalkyl, C 6 -C 18 -alkylaryl; R 6 ═C 2 -C 18 -alkylene, C 6 -C 18 -arylene, C 6 -C 18 -alkarylene and/or C 6 -C 18 -aralkylene. Methods for the production of said addition compounds and the use thereof are also disclosed. |