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filingDate 2010-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2011-10-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2011240518-A1
titleOfInvention Gasoline hydrodesulfurization and membrane unit to reduce mercaptan type sulfur
abstract A process for the hydrodesulfurization of gasoline is disclosed, the process including: feeding (1) a cracked naphtha containing mercaptans and other organic sulfur compounds and (2) hydrogen to a first hydrodesulfurization reactor containing one or more beds of a hydrodesulfurization catalyst; contacting sulfur compounds comprising the other organic sulfur compounds in the cracked naphtha with hydrogen in the presence of a hydrodesulfurization catalyst to convert a portion of the other organic sulfur compounds to hydrogen sulfide; withdrawing from the hydrodesulfurization reactor an effluent comprising hydrocarbons and hydrogen sulfide. The effluent from the hydrodesulfurization reactor is fed to a membrane separation system containing a membrane for partitioning the hydrocarbons from the hydrogen sulfide. For example, the membrane may be selective to hydrogen sulfide, to separate a permeate fraction comprising hydrogen sulfide from a residue fraction comprising the hydrocarbons.
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