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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ed927d07c38e2a65347f524d35abbda6
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publicationDate 2011-09-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2011220550-A1
titleOfInvention Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
abstract Deep desulfurization of hydrocarbon feeds containing undesired organosulfur compounds to produce a hydrocarbon product having low levels of sulfur, i.e., 15 ppmw or less of sulfur, is achieved by first contacting the entire feed with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to remove the labile organosulfur compounds. A flashing column downstream of the hydrodesulfurization reaction zone fractionates the effluent at a target cut point temperature to obtain two hydrocarbon fuel fractions. A first fraction boiling at or above the target cut point temperature contains the remaining refractory organosulfur compounds. A second fraction boiling below the target cut point temperature is substantially free of organosulfur compounds, since the organosulfur compounds boiling in the range of this fraction were the labile organosulfur compounds which were initially removed by mild hydrodesulfurization. The first fraction is contacted with an oxidizing agent and an active metal catalyst in an oxidation reaction zone to convert the refractory organosulfur compounds to oxidized organosulfur compounds. These oxidized organosulfur compounds are subsequently removed, producing a stream containing an ultra-low level of organosulfur compounds. The two streams can be combined to obtain a full range hydrocarbon product having an ultra-low level of organosulfur compounds.
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