http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2011172456-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_8e0bf0928b608797b70bbc2b91c7e52e |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C231-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-10 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-95 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C65-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C231-12 |
filingDate | 2009-05-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_305ffcd9588e3a633ef064fac1e59df5 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_89560156d16fc7310273819a410c091c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_223fa0768f67504ca8e8025f5040d668 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7e19d1ef58f6990f08f11054f1a5a978 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fba1b05c0644d4a3042819aff6442e87 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_439bc70396ee49b5a95e9014d1be1d64 |
publicationDate | 2011-07-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-2011172456-A1 |
titleOfInvention | Method for Producing Aromatic and Heteroaromatic Carboxylic Acids, Carboxylic Acid Esters and Carboxylic Acid Amides |
abstract | Process for the preparation of aromatic and heteroaromatic carboxylic acids, carboxylic acid esters and carboxamides by the reaction of aromatic or heteroaromatic halides R—X n , in which n=integer from 1 to 6, R=substituted or unsubstituted and aromatic or heteroaromatic radical and X=chlorine, bromine or iodine atom, with carbon monoxide and water, ammonia, alcohols or amines in the presence of bases and zero-valent or divalent palladium compounds and bidentate diphosphanes or complexes of zero-valent or divalent palladium with bidentate diphosphanes, in which use is made of bidentate diphosphanes n (R 1 —)(R 2 —)P—Y—P(—R 3 )(—R 4 )n n in which R 1 to R 4 =unsubstituted aryl radicals or aryl radicals substituted with at least one radical exhibiting a positive resonance effect or a positive inductive effect, or unsubstituted or substituted cycloalkyl radicals, and Y=hydrocarbon group with a total of 2 to 20 carbon atoms, in which at least one of the carbon atoms carries only one or no hydrogen atom as substituent; except for the reaction of 4-bromo-3-difluoromethyl-1-methylpyrazole with 2-(3,4,5-trifluorophenyl)aniline and carbon monoxide to give N-[2-(3,4,5-trifluorophenyl)phenyl]-3-difluoromethyl-1-methylpyrazole-4-carboxamide. |
priorityDate | 2008-05-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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