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filingDate 2009-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_af6d2989317e3a03c68708685ffbc2c1
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publicationDate 2011-04-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2011097524-A1
titleOfInvention Process for Making Opaque Polyester Film
abstract The invention relates to a process for making an opaque and glossy film from a thermoplastic polyester composition, comprising the steps of a) extruding the polyester composition through a slot die, and quenching to form a substantially amorphous film having a crystallinity of at most 5%; b) rapidly heating the amorphous film to a drawing temperature in the range from T g to (T g +50)° C. while applying a draw ratio in the range of from λ initiation to λ max. in longitudinal direction, and a drawing rate of at least 1 m/min to form an oriented film showing stress-whitening, wherein λ initiation is the draw ratio at which a transfer from a transparent product to a stress-whitened product occurs and λ max. is the draw ratio at which failure of the stress whitened film occurs; and c) heat-setting the oriented stress-whitened film; the thermoplastic polyester composition substantially consisting of at least one crystallisable polyester derived from at least one aliphatic diol and at least one aromatic dicarboxylic acid. n With this process it is possible to make a unitary, glossy, opaque film from a polyester composition that does not contain void-forming additives like high amounts of fine pigment particles or dispersed non-miscible polymer particles. The film obtained also has very good mechanical properties. It is a further advantage that the process can be performed continuously on conventional extrusion and stretching equipment used for making transparent film from polyesters. n The invention also relates to an opaque polyester film obtainable by said process.
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