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filingDate 2007-09-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2009-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2009069617-A1
titleOfInvention Processes for the Isomerization of Normal Butane to Isobutane
abstract In a normal butane isomerization process where the isomerization effluent ( 108, 114 ) is fractionated in a deisobutanizer ( 116 ) operated such that a lower boiling fraction ( 118 ) is provided containing at least 80 mass-% isobutane and a higher boiling fraction ( 122 ) containing normal butane and at least 10 mass-% isobutane. The higher boiling fraction ( 122 ) is contacted with a selectively permeable membrane ( 124 ) to provide a permeate ( 126 ) containing normal butane-containing and a retentate ( 128 ) containing at least 80 mass-% isobutane. The preferred membranes are sieving membranes having a C 4 Permeate Flow Index of at least 0.01 and a C 4 Permeate Flow Ratio of at least 1.25:1.
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