http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2008300376-A1

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classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J27-02
classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-0201
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filingDate 2006-11-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_76b86418d5e1dd6129a15d1e3d770481
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_75719165cac891a8684e9f6d239f88f8
publicationDate 2008-12-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2008300376-A1
titleOfInvention Method for the Production of Multimetal Cyanide Compounds
abstract Process for preparing multimetal cyanide compounds, which comprises the steps n a) reaction of the aqueous solution of a metal salt of the general formula (I) n M 1 g X n   (I) n with the aqueous solution of a cyanometalate compound of the general formula (II) n M 3 r [M 2 (CN) b ] d , ,   (II) n if appropriate in the presence of organic ligands, organic additives and/or surface-active agents, n to form a multimetal cyanide compound of the general formula (III) n M 1 a [M 2 (CN) b ] d .fM 1 j X k .h(H 2 O).eL.zP   (III) n b) reaction of the multimetal cyanide compound of the general formula (III) with a salt of the general formula (IV) n M 4 s Y t ,   (IV) n which is different from (II) where n M 1 is a metal ion selected from the group consisting of Zn 2+ , Fe 2+ , Fe 3+ , Co 2+ , Co 3+ , Ni 2+ , Mn 2+ , Sn 2+ , Sn 4+ , Pb 2+ , Al 3+ , Sr 2+ , Cr 3+ , Cd 2+ , Cu 2+ , La 3+ , Ce 3+ , Ce 4+ , Eu 3+ , Mg 2+ , Ti 4+ , Ag + , Rh 2+ , Ru 2+ , Ru 3+ , Pd 2+ n M 2 is a metal ion selected from the group consisting of Fe 2+ , Fe 3+ , Co 2+ , Co 3+ , Mn 2+ , Mn 3+ , Ni 2+ , Cr 2+ , Cr 3+ , Rh 3+ , Ru 2+ , Ir 3+ and M 1 and M 2 are identical or different, n X is an anion, selected from the group consisting of halide, hydroxide, sulfate, hydrogensulfate, carbonate, hydrogencarbonate, cyanide, thiocyanate, isocyanate, cyanate, carboxylate, oxalate, nitrate and nitrite (NO 2 —) or a mixture of two or more of the abovementioned anions or a mixture of one or more of the abovementioned anions with an uncharged species selected from among CO, H 2 O and NO, n Y is an anion which is different from X and is selected from the group consisting of halide, sulfate, hydrogensulfate, disulfate, sulfite, sulfonate, (═RSO 3 —where R═C1-C20-alkyl, aryl, C1-C2-alkylaryl), carbonate, hydrogencarbonate, cyanide, thiocyanate, isocyanate, isothiocyanate, cyanate, carboxylate, oxalate, nitrate, nitrite, phosphate, hydrogenphosphate, dihydrogenphosphate, diphosphate, borate, tetraborate, perchlorate, tetrafluoroborate, hexafluorophosphate, tetraphenylborate, n L is a water-miscible ligand selected from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, polyesters, polycarbonate, ureas, amides, nitriles, and sulfides and mixtures thereof, n P is an organic additive, selected from the group consisting of polyethers, polyesters, polycarbonates, polyalkylene glycol sorbitan esters, polyalkylene glycol glycidyl ethers, polyacrylamide, poly(acrylamide-co-acrylic acid), polyacrylic acid, poly(acrylamide-co-maleic acid), polyacrylonitrile, polyalkyl acrylate, polyalkyl methacrylate, polyvinyl methyl ether, polyvinyl ethyl ether, polyvinyl acetate, polyvinyl alcohol, poly-N-vinylpyrrolidone, poly(N-vinylpyrrolidone-co-acrylic acid), polyvinyl methyl ketone, poly(4-vinylphenol), poly(acrylic acid-co-styrene), oxazoline polymers, polyalkylenimines, maleic acid and maleic anhydride copolymers, hydroxyethylcellulose, polyacetates, ionic surface- and interface-active compounds, bile acids, and their salts, esters and amides, carboxylic esters of polyhydric alcohols and glycosides, n and n a, b, d, g, n, r, s, j, k and t are integers or fractions greater than zero, n e, f, h and z are integers or fractions greater than or equal to zero n where n a, b, d, g, n, j, k and r and also s and t are selected so that the compound is electrically neutral, n M 3 is hydrogen or an alkali metal or alkaline earth metal, and n M 4 is an alkali metal ion or an ammonium ion (NH 4 + ) or an alkylammonium ion (R 4 N + , R 3 NH + , R 2 NH 2 + , RNH 3 + where R═C1-C20-alkyl).
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priorityDate 2005-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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