abstract |
A method for plugging a permeable zone or leak in a subterranean formation comprises introducing into the formation a cross-linking composition which comprises (a) an aqueous liquid, (b) a pH buffer, (c) a cross-linkable organic polymer, (d) a cross-linking agent which comprises an organic titanate, an organic zirconate, or combinations thereof, and (e) a delay agent which is a hydroxyalkylaminocarboxylic acid. The method can be used over a wide range of pH conditions. |