http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2007015935-A1

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filingDate 2004-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_de2e82cec2560ef06e30d1840e651876
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publicationDate 2007-01-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2007015935-A1
titleOfInvention Method for producing high purity terephthalic acid
abstract In the process for producing a high-purity terephthalic acid of the invention, a slurry of crude terephthalic acid crystals dispersed in an acetic acid solvent, which is produced by a liquid-phase oxidation of p-alkylbenzene in the acetic acid solvent, is continuously converted into a slurry in water by a mother liquor displacement and then subjected to a catalytic hydrogenation. The acetic acid solvent slurry is introduced into a column equipped with a central shaft having a plurality of stirring blades along a vertical direction thereof from an upper portion of the column. The crude terephthalic acid crystals are allowed to sediment to form a high-concentration zone of terephthalic acid crystals in the column. A displacing water is fed into the column from a bottom portion thereof so as to form an upward flow of water in the column while forming circular flows in the high-concentration zone by rotation of the stirring blades, thereby bringing the terephthalic acid crystals into counter-current contact with the upward flow of water. The terephthalic acid crystals after counter-current contact with the upward flow of water is discharged from a bottom portion of the column together with the displacing water, while simultaneously taking the acetic acid solvent out of a portion of the column disposed above a feed portion for introducing the acetic acid solvent slurry. By the process, the acetic acid solvent of the acetic acid slurry is displaced by water in a high degree of mother liquor displacement.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2011108420-A1
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2011145424-A1
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9339778-B2
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