http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2006149010-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_8900b7ff9550171b63a4dae15fa503ab http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1f6701a6a0090767f16838abf5137777 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_171e15487f7fa8fd788a20eb7eb4f1a9 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_f6b04ee566d38c9b394da6c904c9cb8a |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F36-06 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-56 |
filingDate | 2005-12-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8db059b5f4b0a2c54d0af101c5bd501b http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1adb06f1c49ca0ad6204fe1565e34fb7 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_516fed78755b72f35ea759261ad1cccb http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e7a545349bd3b219581119025f52fdfd |
publicationDate | 2006-07-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-2006149010-A1 |
titleOfInvention | Catalyst for synthesizing high trans polymers |
abstract | The process and catalyst of this invention can be utilized to synthesize homo and copolymers of conjugated diene monomers and vinyl aromatic monomers having high trans contents of greater than 60% with low melting points. These homo and copolymers of conjugated diene monomers and vinyl aromatic monomers can be utilized in tire tread and sidewall rubbers that exhibit outstanding wear and tear characteristics in the tread and excellent flexing properties in the sidewall. The rubber polymers of this invention are made utilizing an improved catalyst system. This catalyst system is comprised of (a) organo aluminum compounds, (b) organo lithium compounds, (c) a barium compound selected from barium salts of (i) di(ethylene glycol) ethyl ether, (ii) di(ethylene glycol) propyl ether, (iii) di(ethylene glycol) hexyl ether, (iv) di(N,N-dimethyl amino glycol) ethyl ether, (v) menthol and thymol in the presence of polar modifier consisting of water, alcohols, amines, thiols, phosphates and phosphites. The trans polymers and copolymers of this invention made with the above catalyst system typically have a glass transition temperature ranging from −97° C. to −40° C., a melt temperature ranging from −30° C. to +30° C., and a number average molecular weight from 20,000 to 250,000. The inclusion of such polar modifiers in the barium catalyst system results in a high styrene content in copolymerization, a high trans content, and high molecular weight. Copolymers of conjugated diolefin monomers and vinyl aromatic monomers made with the catalyst system of this invention also have a tapered macrostructure. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7884168-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11001654-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2010206443-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11008445-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2008216934-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111212860-A |
priorityDate | 2004-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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