http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2006002846-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_114e4423ec77cbc8dab9d0a98909704e |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C01B15-01 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C01B15-01 |
filingDate | 2004-06-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_270d716717cd7ea4790166b6db42cf8b http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2715d67851effae9bd7cdc98e79a167c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6ca6e07d5084befdca9ed9e7f4edf4e8 |
publicationDate | 2006-01-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-2006002846-A1 |
titleOfInvention | Process for preparing hydrogen peroxide |
abstract | The present invention discloses a process for the production of hydrogen peroxide from hydrazine hydrate or hydrazine salt, represented by a general formula:n nN 2 H 4 .nX,n nwherein, X is H 2 O, H 2 SO 4 , HNO 3 , HCl, HBr, HI or CH 3 COOH; n is 0.5, 1 or 2; N is nitrogen; H is hydrogen; S is sulfur; Cl is chlorine; Br is bromine; and I is iodine, by its liquid phase oxidation with oxygen, using a solid catalyst comprising palladium but with or without halogen promoter, in an aqueous reaction medium with or without comprising a mineral acid and/or halide anions, which comprises: n i) contacting the solid catalyst with a hydrazine hydrate or hydrazine salt and oxygen containing gas selected from oxygen, air and oxygen enriched air, in aqueous reaction medium at the following reaction conditions: the concentration of hydrazine hydrate or hydrazine salt in the reaction medium above 0.001 mol/dm 3 , the concentration of mineral acid in the reaction medium in the range from zero mol/dm 3 to 10 mol/dm 3 , the concentration of halide anions added to the reaction medium in the range from zero mmol/dm 3 to 100 mmol/dm 3 , the concentration of the solid catalyst in the reaction medium in the range from 0.01 g/dm 3 to 100 g/dm 3 , the space velocity of the oxygen containing gas in the range from 100 cm 3 /g catalyst/h to 100,000 cm 3 /g catalyst/h, the mass ratio of hydrazine hydrate or hydrazine salt to solid catalyst in the range from 0.01 to 100, the temperature below 100° C., the pressure at least 0.95 atm, and the reaction contact time above 0.02 h; and ii) separating the H 2 O 2 from the reaction mixture. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103706356-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106475095-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-109603869-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2010056200-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110006880-A |
priorityDate | 2004-06-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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