http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2004077909-A1

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filingDate 2003-10-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d36169dac41b2e8a5b8b14870484e9bf
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publicationDate 2004-04-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-2004077909-A1
titleOfInvention Process for selective production of propylene from hydrocarbon fractions with four carbon atoms
abstract For the selective production of propylene from an olefinic C 4 fraction, a process is implemented that successively comprises: n 1) the selective hydrogenation of butadiene with isomerization of butene-1 into butene-2; n 2) the separation by distillation of a mixture that is rich in isobutene and butene-1 at the top and a fraction that is rich in butene-2 at the bottom; n 3) the skeletal isomerization of isobutene into n-butenes on the top fraction, with recycling in stage 1; and n 4) the metathesis of the butene-2-rich fraction with ethylene. n The advantage of this process is to produce in a very selective way polymerization-quality propylene from all of the olefinic compounds of a C 4 fraction, including isobutene.
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Total number of triples: 35.