abstract |
This invention is a solution process for the preparation of ethylene-a-olefin-diolefin copolymers comprising contacting ethylene, one or more a-olefin monomer, and one or more cyclic diene monomer, with a catalyst composition comprising a bridged, bis(cyclopentadienyl) zirconium compound having an unsubstituted cyclopentadienyl ligand, a multiply substituted cyclopentadienyl ligand, said ligands bridged by a covalent bridging group containing one or more Group 14 element, and two uninegative, activation reactive ligands and a catalyst activator compound. The invention process exhibits high catalyst activity, high comonomer incorporation and high diene monomer conversion rates and is particularly suitable for the preparation of elastomeric ethylene-propylene or ethylene-propylene-diene monomer elastomers. |