| abstract |
Compounds, compositions and methods of use thereof are provided, the compounds comprising a hydrophobically modified polyelectrolyte comprising a nonionic monomer, an ionic monomer, a monomer having the structure of Formula 1, and a monomer having the structure of Formula 2,wherein R1, R2, R3, R5, R6, and R7 are independently hydrogen, unsubstituted alkyl, substituted alkyl, carbonyl, carboxyl, aryl, or alkaryl; R4 is linear C3 to C30 alkyl; R8 is branched C3 to C30 alkyl; X1 and X2 areindependently —C(O)O—, —C(O)NR9—, —O—, —C(R9)2O—, -arylene-, -arylene-C(R9)2O—, -arylene-C(R9)2N(R10)— or -arylene-C(R9)2N+(R10)2—; R9 and R10 is independently hydrogen or a C1 to C4 alkyl; and wherein a molar ratio of the monomer of Formula 1 to the monomer of Formula 2 is from about 1.5:1 to about 15:1. The compounds are useful as viscosifying agents in oil and gas applications. |