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filingDate 2021-01-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2021-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-11027270-B1
titleOfInvention Method of performing coupling reactions
abstract A method of preparing an amalgamated transition metal layered double hydroxide (LDH)@Y-zeolite hybrid catalyst is provided. The method includes combining a transition metal with aluminum nitrate and precipitating using an alkali under ultrasound irradiation and an inert atmosphere to form a transition metal-containing LDH catalyst. A Y-zeolite is pretreated by an ion exchange process utilizing ammonia prior to calcination at temperature (250-1000° C.) under an inert atmosphere to form an H—Y-zeolite. Followed by refluxing the transition metal-containing LDH catalyst together with the H—Y-zeolite at 50° C. for a predetermined time to form a precipitate. The precipitate is filtering and washing with distilled water to obtain the amalgamated transitional metal LDH@Y-zeolite hybrid catalyst. The disclosure also relates to a method for performing a terminal alkyne dehydrogenation coupling reaction involving a synergetic effect of a bill mill and an amalgamated transition metal layered double hydroxide (LDH)@Y-zeolite hybrid catalyst.
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