abstract |
Bimetallic oxidation catalyst devices include a support body, one or more metal A bulk deposits disposed on the support body, and a plurality of metal B atomic clusters disposed on the surface of each of the metal A bulk deposits. Metal A and metal B are different metals each selected from the group consisting of platinum group metals (PGM), Ag, Au, Ni, Co, and Cu, and substantially no metal B is deposited on the support body. At least 85% by weight of the metal B atomic clusters comprise up to 10 atoms and the maximum metal B atomic cluster size is 200 metal B atoms. The combined loading of metal A and metal B can be less than 1.5% by weight relative to the weight of the support body. Metal A can include Pd, Rh, Rh, or Pd, and metal B can include Pt, Pt, Ag, or Ag. |