http://rdf.ncbi.nlm.nih.gov/pubchem/patent/TW-534923-B

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filingDate 1999-09-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2003-06-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6663111cd65431263da584229c4642f1
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fd0c80206e667d494b92552b3258a72c
publicationDate 2003-06-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber TW-534923-B
titleOfInvention Vinyl monomer polymerization inhibition using hindered hydroxylamines
abstract It has been discovered that the polymerization of vinyl aromatic compounds, such as styrene, may be inhibited by the addition of a composition that contains a hindered hydroxylamine, and, optionally, a synergist together with the hindered hydroxylamine. In one embodiment of the invention, the hindered N,N-disubstituted hydroxylamine has the formula: [(R1R2R3)C]2N-OH, where R1, R2, and R3 are independently selected from the group consisting of hydrogen, straight, branched or cyclic alkyl, aryl, aralkyl, and alkaryl moieties; where no more than two of R1, R2, and R3 on each C can be hydrogen at a time; where one or more of R1, R2, and R3 on one C may be joined to a R1, R2, and R3 on the other C to form a cyclic moiety selected from the group consisting of alkylene, and aralkylene moieties; where any two of the R1, R2, and R3 on any one C may be joined together to form a cycloalkyl; where any of the above definitions of R1, R2, and R3 may contain one or more heteroatoms selected from the group consisting of N, O and S; and where the total number of carbon atoms in the hindered N,N-disubstituted hydroxylamine ranges from 6 to 70. Optional synergists may include alkyl-substituted hydroxyarenes such as 2,5-di-tert-butylhydroquinone, and hydrogen transfer agents such as 1,2,3,4-tetrahydronaphthalene; and the like, and mixtures thereof.
priorityDate 1998-09-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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