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publicationDate 2002-08-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber TW-497171-B
titleOfInvention Elimination of photo-induced electrochemical dissolution in chemical mechanical polishing
abstract Eliminating exposure of PN junctions to light capable of invoking a photovoltaic effect and/or inhibiting the oxidation and reduction reactions induced by the photovoltaic effect prevents the electrochemical dissolution of metal components on semiconductor devices by electrolysis. A darkened enclosure for use on tools for wafer CMP, brush cleaning, unloading, and rinsing will eliminate exposure. Alternatively, illumination of a semiconductor wafer can be limited to wavelengths of light that do not provide enough energy to induce a photovoltaic effect. An inhibitor in the CMP slurry and/or post-CMP water rinse blocks the oxidation and/or reduction reactions. A blocking agent, such as a high molecular weight surfactant, will interfere with both the oxidation and reduction reactions at the metal surface. Also, a poisoning agent will impede the reduction portion of electrolysis.
priorityDate 1998-02-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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