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filingDate 1996-10-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1999-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f6b075ff7bb5417d8feeef9e145c5c38
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publicationDate 1999-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber TW-360669-B
titleOfInvention Readily supportable metal complexes
abstract Metal complexes useful as supported olefin polymerization catalysts corresponding to the formula, wherein: M is titanium in the +2, +3 or +4 formal oxidation state; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula, -(ER2)m-, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C1-20 hydrocarbyl, and C1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C1-20 hydrocarbyloxy, and m is an integer from 1 to 3; Y is NR*, wherein R* is C1-10 hydrocarbyl; R' independently in each occurrence is selected from the group consisting of hydrogen, hydrocarbyl, silyl, germyl, cyano, halo and combination thereof, said R' having up to 20 non-hydrogen atoms each, or adjacent R' groups together form a divalent derivative that is a hydrocarbadiyl, siladiyl or germadiyl group; wherein n is 1, p is 0 and X' is η4-1,4-diphenyl-1,3-butadiene; η4-1,3-pentadiene; η4-1-phenyl-1,3-pentadiene; η4-1,4-dibenzyl-1,3-butadiene; η4-2,4-hexadiene; η4-3-methyl-1,3-pentadiene; η4-1,4-ditolyl-1,3-butadiene; or η4-1,4-bis(trimethylsilyl)-1,3-butadiene, and X' forms a π-complex with M and M is in the +2 formal oxidation state; when n is 0, p is 1 or 2, and X'' each occurrence is chloride, methyl, benzyl, phenyl, tolyl, t-butyl, methoxide, or trimethylsilyl or two X'' groups together are 1,4-butanediyl, s-cis(1,3-butadiene), or s-cis(2,3-dimethyl-1,3-butadiene), and M is in the +3 or +4 formal oxidation state.
priorityDate 1995-10-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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