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publicationDate 2018-05-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber TW-201815689-A
titleOfInvention Method for preparing cathode material with low BET surface area and high packing density and specific cathode material
abstract A method of preparing a powdery mixed oxide A having the general formula Li 1+x (Ni a Co b Mn c )B d Na e O 2 , wherein 0<x 0.5;0<a 1;0 b 1;0<c 1;0.001 d 0.1,0.001<e 0.2, and having a BET surface area of 10 to 50 m 2 /g and a packing density of 250 to 700 g/l, which comprises a) providing an oxidizable species of lithium, manganese, nickel and sodium contained in individual proportions corresponding to the formula And a solution of a hydrolyzable metal compound and boric acid, b) atomizing the solution with an atomizing agent gas to provide an aerosol, c) reacting the aerosol with a flame in a reaction space, wherein the flame is derived from a combustion gas and air The mixture is obtained, and the total amount of oxygen therein is at least sufficient to completely convert the combustion gas and the metal compound, d) cooling the reaction stream and subsequently removing solids from the reaction stream.n n n a powdery mixed oxide of the formula Li 1+x (Ni a Co b Mn c )B d Na e O 2 wherein 0<x 0.5;0<a 1;0 b 1;0<c 1;0.001 d 0.1;0.001<e 0.2 having a BET surface area of 0.1 to 5 m 2 /g, and a packing density of 1000 to 2500 g/l, and a mixed oxide particle in a near surface layer having a depth of about 5 nm therein reaches a sodium concentration determined by XPS-ESCA Its maximum value and decreases inward.
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