http://rdf.ncbi.nlm.nih.gov/pubchem/patent/TW-201433560-A

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filingDate 2011-11-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2014-09-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber TW-201433560-A
titleOfInvention Effective substitution of rare earth metals in compositions and materials for electronic applications
abstract Embodiments disclosed herein include methods of modifying synthetic garnets for RF applications to reduce or eliminate bismuth or other rare earth metals in the garnet without adversely affecting the magnetic properties of the material. Some embodiments include the substitution of a moiety on a dodecahedral site with deuterium and the introduction of one or more high-valent ions to an octahedral and tetrahedral site. Calcium can also be added to the dodecahedral site for valence compensation by high valence ions, which can effectively replace all or most of the yttrium (Y) in the garnet of the microwave device. Synthetic garnets containing modified yttrium (Y) can be used in a variety of microwave magnetic devices such as circulators, isolators and resonators.
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