abstract |
This disclosure relates to a method for rejuvenating a catalyst, comprising contacting the catalyst with a gaseous feedstock at rejuvenation conditions for at least one hour to form a rejuvenated catalyst and a gaseous product, wherein the catalyst comprises at least 10 wt. % of a molecular sieve, wherein the catalyst prior to the contacting step comprises from 0. 001 wt. % to 45 wt. % of hydrocarbons and 0. 001 to 10 wt. % nitrogen containing components based on the total weight of the catalyst prior to the contacting step, wherein the molecular sieve comprises at least one of a MCM-22 family molecular sieve, a molecular sieve having a framework type of *BEA, a molecular sieve having a framework type of FAU, and a molecular sieve having a framework type of MOR, wherein the gaseous feedstock comprises at least one of N2, H2, alkane, He, Ar, CO, and CO2, wherein the gaseous product has at least a portion of the gaseous feedstock and at least a portion of the hydrocarbons of the catalyst and at least a portion of the nitrogen containing components of the catalyst, wherein the rejuvenation conditions comprise a temperature in the range from about 400 to 600 DEG C, a pressure in the range from about 101. 3 kPa-a to 10130 kPa-a, a space hourly velocity in the range of from 0. 05 to 10 hr-1. |