http://rdf.ncbi.nlm.nih.gov/pubchem/patent/TW-200804321-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2baf849d216e689ecc40ccc931a7a7bc |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D277-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/A01N43-78 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/A01N43-78 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D277-32 |
filingDate | 2007-03-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3e547371754d0ab23c3cfbf19a4bf528 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_860742eadf896c534622c26d43bef808 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_636d263cafb7e37daa038fe158c8abc5 |
publicationDate | 2008-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | TW-200804321-A |
titleOfInvention | Method for preferential production of geometric isomers and isolation method |
abstract | A method for the preferential production of the Z form of a compound represented by the formula (5) [in the formula (5), Q, A and B have the same meanings as stated below], by reacting an acrylonitrile compound represented by the formula (1): [in the formula (1), Q represents unsubstituted or substituted phenyl or heterocyclyl, in particular 4-thiazolyl, 1- or 3-pyrazolyl, 1,3-oxazolyl-4-yl, phenyl, pyridyl or the like, A represents pyrazolyl, thiazolyl or the like, and B represents alkylcarbonyl or the like] with a compound represented by formula (3) [in the formula (3), B represents alkylcarbonyl or the like] or a compound represented by the formula (4) [in the formula (4), B has the same meaning as aforesaid], in the presence of a compound represented by the formula (2) [in the formula (2) R represents H, dimetylamino and the like], and a method for the isolation of geometric isomers, wherein, by dissolving or suspending a geometric isomer mixture of an acrylonitrile compound represented by the formula (5) in an alcohol or a solvent containing an alcohol, the E form is preferentially decomposed and the Z form is isolated, and wherein the decomposition product can be simply recovered by normal operations and reutilized. |
priorityDate | 2006-03-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 211.