http://rdf.ncbi.nlm.nih.gov/pubchem/patent/SE-9600574-D0
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_6cebf930972fc225227a1b5ec6a386c1 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2aa816b8bf7d6149f9d14cf2a8639732 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_20449b555292cc6335dcb32df46c439e |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07J75-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07J75-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07J- |
filingDate | 1996-02-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c29b20007509a01691fbc4b340fe571c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5036f46ed0ee2db7117060965ce770d3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2c3263c1deb8b5da7dc4aae601a9004a |
publicationDate | 1996-02-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | SE-9600574-D0 |
titleOfInvention | Method of oxidation |
abstract | Oxidation of 3~b-hydroxy steroids of formula (I) to the corresponding 4-en-3-one derivatives of formula (II) takes place in a catalysed process at a low temperature in the presence of a carbonyl compound and a catalytic system containing a ruthenium (II) complex. R1 = H or methyl; R2 = methyl or ethyl; R3 = 1-8C alkyl, 1-10C alkenyl, hydroxy, ester, acyl, ~a-substituted acetyl, furanyl or di(1-8C)alkylamino; R4 = H, 1-8C alkyl, 1-10C alkenyl, 2-4C alkynyl, hydroxy or ester or R3 + R4 = keto, alkylidene, carboxyalkylidene or CH2CH2COO (forming a spiro-lactone together with C-17); R5 = H, 1-8C alkyl, alkylidene or hydroxy or R4 + R5 = OCR2O (forming a ketal together with C-17 and C-16); R6 = H, 1-8C alkyl or hydroxy or R5 + R6 = alkylidene. |
priorityDate | 1996-02-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 24.