http://rdf.ncbi.nlm.nih.gov/pubchem/patent/SE-8306740-D0

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filingDate 1983-12-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_51d7f37be9f9f463a4c2112a0d974650
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publicationDate 1983-12-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber SE-8306740-D0
titleOfInvention 2-THIACEPHEMS AND (5R) PENEMS DERIVATIVES
abstract A new process is described for the preparation of (5R)-penem derivatives of the general formula I: <IMAGE> I wherein R1 represents a hydrogen atom or an organic group; R2 represents a hydrogen atom or a carboxy protecting group and Y represents a hydrogen or halogen atom or an organic group. A 2-thiacephem derivative of the general formula II: <IMAGE> II wherein R1, R2 and Y have the meanings/given above is oxidized by means of organic peracids to the corresponding sulphone of the general formula III: <IMAGE> III which is subsequently submitted to a desulphurative ring contraction by extrusion of SO2 to give exclusively the desired (5R)-penem derivatives of the general formula I.
priorityDate 1982-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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