http://rdf.ncbi.nlm.nih.gov/pubchem/patent/SE-7510968-L

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filingDate 1975-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_502ca9f8d67f98432fe25afd5ee5b539
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_19691b18326ea5103634ebe7bc160c03
publicationDate 1976-04-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber SE-7510968-L
titleOfInvention THERMOPLASTIC POYSILOXANE LOADERS
abstract 1517557 Polysiloxane elastomers having organic linkages RHONE POULENC INDUSTRIES 30 Sept 1975 [1 Oct 1974 11 Feb 1975] 40055/75 Heading C3T A thermoplastic polysiloxane elastomer contains units of the formula wherein each R<0> is a C2-10 alkylene or cycloalkylene radical optionally bearing 1-4 Cl or F atoms; each # is a direct bond or -SiR2-, -SiR2O-, -SiR2-(CH2)1-3- or -SiR2- C6H4- (R being Me or Ph); each R<1> is an alkyl, haloalkyl, cyanoalkyl, aryl or haloaryl radical, each R<2> is a C1-4 alkylene or alkylidene radical; each X is -O-, -S- or -NR<4>- or -CO-O-, -CO-S- -CS-O- or -OS-S- attached to R<2> via O or S (R<4> being H or C1-6 alkyl); each # has 1-30 C atoms and is (i) an optionally chlorinated alkylene, alkylidene, cycloalkylene or arylene radical or a a mono- or poly-cyclic divalent saturated, unsaturated or aromatic heterocyclic radial, or two or more such radicals linked directly or via -O-, -S-, -NR<4>-, -COO-, -CONR<4>-, O -SO2-, -N=N-, -N=N-, -CO- or -PO(R<5>)- (R<5> being C1-4 alkyl, cyclohexyl or phenyl) or (ii) a benzenetriyl, naphthalenetriyl, pyridinetriyl or =C6H3-E-C6H4- radical (E being C1-4 alkylene or alkylidene, -O-, -S-, -COO-, -SO2-, -CO- or -CONH-) in which one valency is attached to X and the other two to T below when T is each # is -O-CO-0-, -NR<4>-CO-NR<4>-, -NR<4>-CO-O, -O-CO-CO-O-, -SCO-CO-S-, -NR<4>-CO-CO-NR<4>, -T-R<11>-T-, wherein R<11>, R<111> and R<1111> are di-, tri- and tetra-valent organic radicals and each T is -CO-O-, -CO-S-, -CO-NR<4>-, -NH-CO-NR<4>-, -NH-CO-O- or -NH-CO-S- attached at either end to a divalent group #, or is attached via the -CO- groups to trivalent #; and n is 1-2000. They are prepared by reaction of the silanes in which each R is a C2-10 ethylenically unsaturated organic radical, with the siloxanes H-SiR<1>2-(OSiR<1>2)n-H. In examples silanes having two groups CH2=CH-SiMe2-CH2O- linked by the sequences (Examples 1 and 2 and 8-11), (Examples 3 and 4), (Example 5), (Example 6) and (Example 7), are added in place of a Pt catalyst to siloxanes HMe2Si(OSiMe2)nH, where n is 14 to 37, in toluene, cyclohexane, dioxan or butyl acetate. The products, in the same solvents or chloroform, are cast into films, or moulded into sheets. The unsaturated silanes are the subject of copending Specification 1,517,558.
priorityDate 1974-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 38.