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filingDate 1974-09-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1974-09-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber SE-7411258-L
abstract 1332680 Alkyl adamantanes; tractant compositions SUN OIL CO 13 Nov 1970 [14 Nov 1969 (2) 14 Oct 1970] 54091/70 Headings C5E and C4X C 10 -C 19 saturated adamantane hydrocarbons having 0 to 3 alkyl substituents and/or the corresponding adamantols are reacted with a C 3 -C 20 n-paraffin or C 4 -C 20 isoparaffin in the presence of 96-105% strength H 2 SO 4 at a temperature above the freezing point of the acid but below 100‹ C. to give as products an adamantane hydrocarbon having attached to a bridgehead position the alkyl group derived from the paraffin and/or a hydrocarbon product comprising two adamantane nuclei linked between bridgehead positions by an alkylene -group derived from the paraffin. Compounds of the formula QX and QZQ wherein Q is a C 12 -C 14 alkyl adamantyl group, X is a C 5 -C 8 alkyl group including the structure -(CH 2 ) n CH(CH 3 ) 2 where n is 2-5, and Z is C 5 -C 8 .alkylene group of the structure -(CH 2 ) m -CH.CH 3 -where m is 3-6 are claimed per se. The adamantane hydrocarbon products may be used in tractant compositions optionally with at least one other component selected from: (a) a C 13 -C 40 naphthene having a glass transition temperature of - 90 to - 30‹ C.; and (b) a fully hydrogenated polymer of a C 3 -C 8 olefin. In the examples 1,3- dimethyl adamantane and 3,5-dimethyl adamantol-1 are reacted with C 5 -C 8 n-paraffins, isopentane, 3-methyl-heptane, neohexane, 3- methylpentane and 2,3-dimethylbutane.
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