http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2696778-C1

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filingDate 2018-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2019-08-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2019-08-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2696778-C1
titleOfInvention Method of producing 2,8-bis-cycloalkyl-2,3,8,9,12c,12d-hexahydro-1h,7h-5,11-dioxa-2,3a,4,6,6b,8,9a,10,12,12b-deca-cyclocapenta[e,l]pyrenes
abstract FIELD: chemistry.SUBSTANCE: invention relates to a method of producing 2,8-bis-cycloalkyl-2,3,8,9,12c,12d-hexahydro-1H,7H-5,11-dioxa-2,3a,4,6,6b,8,9a,10,12,12b-deacylacyclopent[e,l]pyrenes of general formula (1), in which 1,3,5-tricycloalkyl-1,3,5-triazinanes are reacted with 4a,5,9a,10-tetrahydro-4H,9H-[1,2,5]oxadiazolo[3,4-b][1,2,5]oxadiazolo[3’,4’:5,6]pyrazino[2,3-e]pyrazine in the medium of CHOH-DMSO in presence of a NiClcatalyst in molar ratio of 1,3,5-tricycloalkyl-1,3,5-triazinane:4a,5,9a,10-tetrahydro-4H,9H-[1,2,5]oxadiazolo[3,4-b][1,2,5]oxadiazolo[3’,4’:5,6]pyrazino[2,3-e]pyrazine:NiCl= 2:1:(0.03–0.07) at room temperature (~20 °C) temperature and atmospheric pressure for 2.5–3.5 hours.EFFECT: technical result is obtaining novel compounds of formula (1), which can be used as candidate compounds for developing drug preparations, luminescent intercalators and a base for designing so-called molecular devices, as well as promising components of explosives and rocket fuels.1 cl, 1 tbl, 3 ex
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