http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2653060-C1

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F232-08
filingDate 2017-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_454d788140a2c26c248db8e4f5b0d725
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_27cdf5e98b1f74c89dbe6145e256034a
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publicationDate 2018-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2653060-C1
titleOfInvention Method for additive copolymerization of norbornene with 5-methoxycarbonylnorbornene
abstract FIELD: biotechnology. n SUBSTANCE: invention relates to the production of additive copolymers of norbornene and its derivatives under the action of catalytic systems based on cationic palladium complexes and borontrifluoride etherate. Use of a catalyst containing a cationic complex (acetylacetonate) bis (triphenylphosphine) palladium tetrafluoroborate of the general formula [(acac)Pd(PPh 3 ) 2 ]BF 4 for carrying out the additive copolymerization of norbornene with 5-methoxycarbonylnorbornene by reaction in an organic solvent medium. As cocatalyst, borontrifluoride etherate of general formula BF 3 ⋅OEt 2 is used. Process is carried out at a molar ratio of boron to palladium, [BF 3 ⋅OEt 2 ] 0 :[Pd] 0 = 20:1 in an organic solvent: mixtures of methylene chloride and toluene. n EFFECT: technical result is the expansion of the arsenal of the copolymers obtained. n 1 cl, 6 ex, 1 tbl
priorityDate 2017-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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