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filingDate 2016-04-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-02-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_79ceb0e563c0b2c0797f42bd1708eeae
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publicationDate 2018-02-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2644894-C2
titleOfInvention Luminescent detector of cations of alkali metals
abstract FIELD: chemistry. n SUBSTANCE: material has a composition (H 3 O) 2 [Zn 4 (ur) (Hfdc) 2 (fdc) 4 ]⋅G, where ur - urotropin, fdc 2- =2,5-furandikarboksilat, G=4DMF⋅14H 2 O⋅2H 2 fdc⋅2ur consists of secondary blocks of the structure {Zn 4 (ur)(COO) 12 }, in which atoms of zinc are coordinated to each atom of urotropine nitrogen, and contains a hydrophobic and hydrophilic cavity. At the same time, in the hydrophilic cavities there are guest hydronium cations capable of substitution for cations of alkali metals. n EFFECT: invention allows to obtain a material that combines the advantages of solid-state fluorescent sensor with a high selectivity and sensitivity towards cations of alkali metals. n 3 dwg, 2 ex
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