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filingDate 2011-12-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-07-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6b824b0e42e55458683e3dce75ccf8bf
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publicationDate 2016-07-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2591700-C2
titleOfInvention Method and catalyst for selective removal of acetylenes from gas streams
abstract FIELD: chemistry. n SUBSTANCE: invention relates to vapour phase method for selective removal of at least 80 mol% of acetylene impurities from incoming gas flow. Said incoming flow includes C2-C9 unsaturated hydrocarbon monoolefin, diolefin and acetylene impurities. Method involves contact of incoming flow in vapour phase at temperature ranging from 250 °C (480 °F) to 900 °C (1,650 °F) with solid catalyst, not containing zinc, and then output of output stream, where output stream maintains at least 95 mol% of C2-C9 unsaturated hydrocarbon mono- and diolefins, but does not contain at least 80 mol% of acetylene impurities. Catalyst contains only following metals: Ni, Fe, alkali metal and optionally alkali-earth element(s), where Ni is contained in an amount of 0.25-20 wt% of dry residue of catalyst, Fe is contained in an amount of 30-75 wt% of dry residue of catalyst. Invention also discloses a catalyst and steam-cycle method for selective removal of acetylene impurities (version). n EFFECT: invention enables selective extraction of majority of acetylene impurities from gas flow without considerable deterioration of degree of extraction of mono-and diolefins. n 18 cl, 2 dwg, 3 tbl, 5 ex
priorityDate 2010-12-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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