http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2579593-C1

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C01B21-0846
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filingDate 2014-12-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-04-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4ccc2ff0be05f53ba8adf18615fba0f7
publicationDate 2016-04-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2579593-C1
titleOfInvention Method of producing nitrosyl chloride compounds of palladium
abstract FIELD: metallurgy. n SUBSTANCE: invention can be used for preparation of organometallic compounds of palladium or palladium-containing materials. Method for preparing nitrosyl-chloride compounds of palladium comprises reacting palladium nitrate with a solution of formic acid or formic acid and sodium formate, or successive reaction with nitrogen oxide NO and with formic acid. Obtained solution is then introduced into a mixture of hydrochloric and glacial acetic acid and precipitated-nitrosyl-chloride compounds of palladium of composition Pd(NO) 2 Cl 2 or Pd(NO)Cl. Palladium nitrosyl-chloride of composition Pd 2 (NO) Cl 2 is prepared by solid-phase decomposition of palladium nitrosyl-chloride of composition Pd(NO)Cl. n EFFECT: invention provides stable production of nitrosyl-chloride compounds of palladium in high yield and in chemically pure homogeneous phase state. n 18 cl, 12 dwg, 10 tbl, 10 ex
priorityDate 2014-12-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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