http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2540089-C1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_3ff5107449ebdaf88df149b6b4c15ec1 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F5-06 |
| filingDate | 2013-10-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2015-01-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_718c7f838db9c74ef528441976297527 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6c809bcba7f2b657e583bdba90605314 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e381ad9604fa76f21ca47b175707a824 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_285194c01584662c885102036417d95f |
| publicationDate | 2015-01-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | RU-2540089-C1 |
| titleOfInvention | Method of obtaining 1-ethyl-3-[(oxyphenyl)methyl]aluminacyclopentanes |
| abstract | FIELD: chemistry. n SUBSTANCE: invention relates to field of organometallic synthesis, namely to method of obtaining 3-(oxyphenyl)methyl-substituted aluminacyclopentanes of general formula (1a-e): a) R 1 =R 3 =H, R 2 =OMe; b) R 1 =H, R 2 =R 3 =OMe; c) R 1 =H, R 2 =OMe, R 3 =OH; d) R 1 =R 2 =R 3 =OMe; e) R 1 =H, R 2 , R 3 =OCH 2 O. Method includes interaction of allylbenzenes with triethylaluminium (AlEt 3 ) in presence of catalyst Cp 2 ZrCl 2 . As allylbenzene used are substituted allylbenzenes, namely: allylanisole, 4-allyl-1,2-dimethoxybenzene, 4-allyl-2-methoxyphenol, 5-allyl-1,2,3-trimethoxybenzene, 5-allyl-1,3-benzodioxol. Reaction is carried out in molar ratio allylbenzene: AlEt 3 : [Zr] = 50:(150-180):(1-2) at temperature 20-22°C for 16 hours in toluene. n EFFECT: invention makes it possible to obtain novel compositions, which can be applied in reactions of stereoregular poly- and oligomerisation of unsaturated compounds, as synthons of fine organic synthesis. n 1 tbl, 1 ex |
| isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10190162-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2646222-C2 |
| priorityDate | 2013-10-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 53.