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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01N21-25
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filingDate 2012-10-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2014-05-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_09449a33ebf3474a71368d9ce8a017a4
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publicationDate 2014-05-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2516656-C1
titleOfInvention Zinc dimeric complexes of crown-containing styryl phenanthrolines as optical sensors on cations of alkali-earth and heavy metals and method of their obtaining
abstract FIELD: chemistry. n SUBSTANCE: described are 15-crown-5- and dithia-18-crown-6-containig 2-methyl-9-styryl phenanthrolines of formula: where as optical sensors on cations of calcium, barium and lead. Claimed compounds are obtained by interaction of ligand of 15-crown-5 or dithia-18-crown-6-containing 2-methyl-9-styryl phenanthroline with zinc perchlorate in acetonitrile with irradiation with red light. n EFFECT: complexes possess properties of highly efficient fluorescent sensors on cations of calcium, barium and lead, which make it possible to visually determine metal cation. n 2 cl, 2 tbl, 2 ex
priorityDate 2012-10-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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