http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2486171-C1

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filingDate 2010-03-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2013-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2013-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2486171-C1
titleOfInvention Method of processing liquid stream after hydroformylation
abstract FIELD: chemistry. n SUBSTANCE: present invention relates to a method of processing a hydroformylation reaction liquid product which contains an aldehyde, high-boiling hydroformylation reaction by-products, a homogeneously dissolved rhodium complex catalyst, an unreacted olefinically unsaturated compound, synthesis gas and volatile by-products, in which a) the liquid stream after hydroformylation is throttled in an expansion tank, wherein there is separation into a liquid phase and a gas phase, b) the liquid phase obtained in the expansion tank is fed into a separation device in which there is separation into a liquid phase, which mainly contains high-boiling hydroformylation reaction by-products, a homogeneously dissolved rhodium complex catalyst and a small amount of aldehyde, and a gas phase which contains the bulk of the aldehyde, and c) a liquid rhodium-containing stream is collected from the separation device. A portion of the liquid rhodium-containing output stream collected from the separation device is removed from the process and the other portion is passed through a filter, and the separated solid substances are removed from the process while the obtained filtrate is returned to the hydroformylation reaction. n EFFECT: method enables to prevent breakdown and/or deactivation of the hydroformylation catalyst. n 13 cl, 1 ex, 1 dwg
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