http://rdf.ncbi.nlm.nih.gov/pubchem/patent/RU-2477273-C2

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C323-52
filingDate 2011-03-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2013-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_62c977bfef4b2f3d6e33dbbab85d1142
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publicationDate 2013-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber RU-2477273-C2
titleOfInvention Sulphur-containing fullerene derivatives and method for production thereof
abstract FIELD: chemistry. n SUBSTANCE: invention relates to sulphur-containing fullerene derivatives of general formula , where X denotes a negative charge (-) which is localised on the fullerene backbone, or a hydrogen atom (H) or a chlorine atom (Cl), where in general formula 1, the fragment S-R 1 is defined as a residue of thio acid or ester thereof, which is bound to the fullerene backbone through a sulphur atom as shown graphically in formula 1, and R 1 has the formula XCOOR; X is a linear or branched alkylene (C n H 2n ; n=1-20) radical; R is a hydrogen atom (H), a linear or branched alkyl (C n H 2n+1 ; n=1-20), an alkenyl (C n H 2n-1 n=1-20) or alkynyl radical (C n H 2n-3 ; n=1-20); is a residue of an amide of thio acid which is bound to the fullerene backbone through a sulphur atom as shown graphically in formula 1, where R 1 has the formula XCONRR'; X is a linear or branched alkylene (C n H 2n ; n=1-20) radical; R and R' are hydrogen atoms or linear or branched alkyl (C n H 2n+1 ; n=1-20) radicals; a thiol residue, where R 1 is a hydrogen atom or a linear or branched alkyl (C n H 2n+1 n=1-20) radical or a saturated (C n H 2n-2 ; n=3-8) ring; a fragment of general formula -S(CH 2 ) n SR, bound to the fullerene backbone thorugh a sulphur atom as shown graphically in formula 1, where R is a hydrogen atom or a linear or branched alkyl (C n H 2n+1 ; n=1-20), alkenyl (C n H 2n-1 ; n=1-20) or alkynyl radical (C n H 2n-3 ; n=1-20), as well as a saturated (C n H 2n-2 ; n=3-8), unsaturated (C n H 2n-4 ; n=5-8, C n H 2n-6 ; n=5-8, C n H 2n-8 ; n=8) or an aromatic ring; a fragment of general formula -S(CH 2 ) n NRR or -S(CH 2 ) n N + RR'R"X", which is bound to the fullerene backbone through a sulphur atom as shown graphically in formula 1, where R, R and R" are hydrogen atoms or linear or branched alkyl (C n H 2n+1 n=1-20) radicals; as well as saturated (C n H 2n-2 ; n=3-8) rings; X" is any anion. The invention also relates to a method of producing said compounds. n EFFECT: novel compounds are obtained, which can be used in biomedical research and in pharmacology, as well as in organic photovoltaics. n 3 cl, 26 dwg, 14 ex
priorityDate 2011-03-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 45.